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Thermal runaway in battery cells

Thermal runaway is a stage of rapid self-heating of the battery cell that in the worst case can result in a fire or explosion. Abuse testing of batteries causes thermal runaway and is tested for product development purposes or product approvals in an open or closed reactor.

Purpose

Our unique pressure vessel offers a cost efficient and quick method to evaluate temperatures, pressure, flow, particles, elemental analysis, total hydrocarbons (THC) and gases released by batteries. It allows battery cells and battery assemblies to be safely tested to gather information needed to assess thermal propagation.

If requested, our vessel can be utilized to obtain UL 9540a approval for your product. This method was designed by UL to evaluate the fire characteristics of a battery energy storage system that undergoes thermal runaway. More information about this test standard can be found on UL's website.

Method

The method for determining the total volume of battery gas produced and the composition of those gases. Maximum pressure in the vessel is recorded as well as temperature and voltage for the tested object. 

The sample is placed inside the reactor and then abused until it goes into thermal runaway. Typically, a heating pad or nail penetration device is used. 

Gas volume

In the closed reactor the maximum pressure and temperature can be used to measure the total volume of gas released by the battery.

For the open reactor a calibrated flow tube with a differential pressure meter and thermocouples are used to calculate the total volume and the mass flow of gas produced by the battery. 

Gas composition

The gas samples are analyzed by FID to measure the THC and Gas Chromatography (GC) to analyze O2, CO, CO2, H2, CH4, C2H4, C2H6, C3H6, C3H8.

Particle size distribution

Particle size distribution can be used for both open and closed reactor by differential low-pressure impactor (DLPI) and measure particles in the range of 0.03 to 15 µm. 

For the open reactor DLPI is attached after the flow tube and the particles in the flow are caught. For the closed reactor ashes are collected from the reactor after the test and blown through a pipe with a constant flow to simulate a ventilation of a battery. The DLPI is attached to the pipe to analyze the particles.

Elemental analysis

The particles from the DLPI and ashes can be analyzed with X-ray fluorescence (XRF) and Induction coupled plasma for elemental analysis and ion chromatography (IC) can be used to analyze the total fluoride content in particles. 

If you have any questions or want more information about the battery abuse tests in a reactor, please contact us by reaching out to our contact person below or fill in the application. 

Deliveries

Raw data for the measurements.

A test report presenting the outcomes of the offered tests, including results from the chemical analysis of gas sampling.

Product approval by UL (optional).

More information

Application of interest

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Service

Thermal runaway in battery cells

Instrument

Gas meters, Air flow / Gas flow, Thermometers, Pressure / Vacuum sensors

Metrology Area

Temperature, Pressure and vacuum, Volume and flow

Certifications

Other Certifications

Standards

Custom tests for product development purposes.

UL 9540a

Price

Price on tender

Delivery time

Normally 2-3 weeks after delivery of the test object.

Preparations

The following information should be prepared:

  • Purpose of the tests, e.g. product development or approval in accordance with UL 9540a.
  • Description of the device under test (DUT)
  • Chemistry of the DUT, e.g. NMC or LFP
  • Capacity of the DUT, i.e. voltage and electric charge (Ah)
  • Dimensions or technical drawing of the test object
  • If and how the DUT should be charged.
Franz Evegren

Contact person

Franz Evegren

Enhetschef

+46 10 516 50 88

Read more about Franz

Contact Franz
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